Heat the oven to 350°F (175°C). Line a 9x13-inch baking pan with parchment paper, leaving overhang on two sides, and lightly grease the exposed sides.
Whisk the melted butter, granulated sugar, and brown sugar in a large bowl until combined. Whisk in the eggs one at a time, then the vanilla, until glossy.
Sift in the cocoa powder, flour, and salt. Fold with a spatula just until no dry streaks remain, then fold in the chocolate chips.
Spread the batter evenly in the prepared pan. Bake for 18 minutes, until the top is just set but the center still looks slightly soft.
While the brownie layer bakes, whisk the eggs, brown sugar, corn syrup, melted butter, vanilla, and salt in a medium bowl until smooth. Stir in the toasted pecan halves.
Pour the pecan topping gently over the hot brownie layer and spread it to the edges, arranging a few pecan halves on top for a bakery finish.
Bake for 25 to 30 minutes more, until the topping is set at the edges and only slightly jiggly in the very center. A skewer in the middle should come out with moist crumbs, not wet batter.
Cool completely in the pan, 2 to 3 hours, then lift out with the parchment and slice into 24 squares with a sharp knife wiped clean between cuts.